Chloe has become the second evictee and had faced the chop against Hardeep after the pair received the most votes from their fellow housemates' nominations.
After leaving the house, Chloe spoke to Emma Willis about her time in the house with Jermaine.
It followed Chloe getting wind that he has been misleading her about the status of his relationship on the outside world in the latest highlights show.
Earlier this week, Jermaine confessed his feelings for Chloe - despite a partner on the outside world.
Chloe and Jermaine's flirtation was previously exposed to the group when they were punished for sending notes to one another.
Chloe wanted a word with Jermaine about what he had told her in the messages.
"I'm just confused by the situation," she says. "I think we need to talk about it. What you told me on the note, is different to what you're telling other people. You're saying to them you have a girlfriend and you're telling me it's f**ked."
"When we get out we'll talk properly," Jermaine told her.
During her chat with Emma tonight, Chloe discovered the truth about Jermaine.
"He told me that it's f**ked," Chloe said of her impression of Jermaine's relationship on the outside world, "I took that to mean he was not with someone but he told other people he had a girlfriend. He was being secretive, and that's how we left it. I wanted to have a conversation."
Emma then revealed to Chloe that Jermaine was in fact married.
"No way... I don't even know what to say to that," Chloe reacted.
Asked if she felt Jermaine led her own, Chloe replied simply: "Yes."
Chloe added: "I don't even have any words at the moment. I think that's disgusting, to be married and then to try and crack on with someone on TV.
"I only found out yesterday he had a girlfriend, but he never ever mentioned marriage."